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Dimethylglyoxime is a chemical compound described by the formula CH₃C(NOH)C(NOH)CH₃. Its abbreviation is dmgH₂ for neutral form, and dmgH for anionic form, where H stands for hydrogen. This colourless solid is the dioxime derivative of the diketone butane-2,3-dione (also known as diacetyl). DmgH₂ is used in the analysis of palladium or nickel. Its coordination complexes are of theoretical interest as models for enzymes and as catalysts. Many related ligands can be prepared from other diketones, e.g. benzil.

Preparation[edit]

Find A Grave, database and images (accessed ), memorial page for Herman August “Red” Jelinek (9 Mar 1927–21 Aug 2003), Find A Grave Memorial no. 87063340, citing Plum Creek Cemetery, Plum, Allegheny County, Pennsylvania, USA; Maintained by DMG (contributor 47752540).

Dimethylglyoxime can be prepared from butanone first by reaction with ethyl nitrite to give biacetyl monoxime. The second oxime is installed using sodium hydroxylamine monosulfonate:^[1]

Complexes[edit]

Dimethylglyoxime is used to detect and quantify nickel, which forms the bright red complex nickel bis(dimethylglyoximate) (Ni(dmgH)₂). The reaction was discovered by L. A. Chugaev in 1905.^[2]

Cobalt complexes have also received much attention. In chloro(pyridine)cobaloxime^[3] the macrocycle [dmgH]₂²⁻ mimics the macrocyclic ligand found in vitamin B12.

References[edit]

1. ^Semon, W. L.; Damerell, V. R. (1930). 'Dimethylglyoxime'. Organic Syntheses. 10: 22. doi:10.15227/orgsyn.010.0022.CS1 maint: multiple names: authors list (link)
2. ^Lev Tschugaeff (1905). 'Über ein neues, empfindliches Reagens auf Nickel'. Berichte der Deutschen Chemischen Gesellschaft. 38 (3): 2520–2522. doi:10.1002/cber.19050380317.
3. ^Girolami, G. S.; Rauchfuss, T.B.; Angelici, R. J. (1999). Synthesis and Technique in Inorganic Chemistry: A Laboratory Manual (3rd ed.). pp. 213–215.

Judith Lewis Herman (born 1942) is an American psychiatrist, researcher, teacher, and author who has focused on the understanding and treatment of incest and traumatic stress. Starcraft 2 mac download.

Herman is Professor of clinical psychiatry at Harvard University Medical School and Director of Training at the Victims of Violence Program in the Department of Psychiatry at the Cambridge Health Alliance in Cambridge, Massachusetts, and a founding member of the Women's Mental Health Collective.

She was the recipient of the 1996 Lifetime Achievement Award from the International Society for Traumatic Stress Studies and the 2000 Woman in Science Award from the American Medical Women's Association. In 2003 she was named a Distinguished Fellow of the American Psychiatric Association.

• 2Publications

Career[edit]

Judith Herman is best known for her contributions to the understanding of trauma and its victims, as set out in her second book, Trauma and Recovery.^[2] There she distinguishes between single-incident traumas – one-off events – which she termed Type I traumas, and complex or repeated traumas (Type II).^[3] Type I trauma, according to the United States Veterans Administration's Center for Post Traumatic Stress Disorder, 'accurately describes the symptoms that result when a person experiences a short-lived psychological trauma'.^[4] Type II – the concept of complex post-traumatic stress disorder (CPTSD) – includes 'the syndrome that follows upon prolonged, repeated trauma'.^[5] Although not yet accepted by DSM-IV as a separate diagnostic category, the notion of complex traumas has been found useful in clinical practice.^[6]

Herman equally influentially set out a three-stage sequence of trauma treatment and recovery. The first involved regaining a sense of safety, whether through a therapeutic relationship, medication, relaxation exercises or a combination of all three.^[7] The second phase involved active work upon the trauma, fostered by that secure base, and employing any of a range of psychological techniques.^[8] The final stage was represented by an advance to a new post-traumatic life,^[9] possibly broadened by the experience of surviving the trauma and all it involved.^[10]

Herman was interviewed by Harry Kreisler, Executive Director of the Institute of International Studies at the University of California at Berkeley, for his ongoing series Conversations with History at the Institute of International Studies, UC Berkeley.^[11] She is currently working on a study into the effects of the justice system on victims of sexual violence, with a view to discovering a better way for victims of crimes to be allowed to interact with what she perceives as an 'adversarial' system of crime and punishment in the U.S.^[12]

Publications[edit]

Books[edit]

• Herman, Judith Lewis (1997) [1992]. Trauma and recovery: the aftermath of violence - from domestic abuse to political terror. New York: BasicBooks. ISBN9780465087303.
• Herman, Judith Lewis (2000) [1981]. Father-daughter incest. Cambridge, Massachusetts: Harvard University Press. ISBN9780674076518.

Book chapters[edit]

• Herman, Judith Lewis (2003), 'Introduction: hidden in plain sight: clinical observations on prostitution', in Farley, Melissa (ed.), Prostitution, trafficking and traumatic stress, Binghamton, New York: Haworth Maltreatment & Trauma Press, pp. 1–16, ISBN9781136764905.Sample pdf.

Articles[edit]

J Herman Dmg Store

• Herman, Judith Lewis (April 2003). 'The mental health of crime victims: impact of legal intervention'. Journal of Traumatic Stress. 16 (2): 159–166. doi:10.1023/A:1022847223135. PMID12699203.
• Herman, Judith Lewis (January 2004). 'Introduction: hidden in plain sight: clinical observations on prostitution'. Journal of Trauma Practice. 2 (3–4): 1–13. doi:10.1300/J189v02n03_01.Sample pdf.
• Herman, Judith Lewis (May 2005). 'Justice from the victim's perspective'. Violence Against Women. 11 (5): 571–602. doi:10.1177/1077801205274450. PMID16043563.
• Herman, Judith Lewis; Dutra, Lissa; Callahan, Kelley; Forman, Evan; Mendelsohn, Michaela (January 2008). 'Core schemas and suicidality in a chronically traumatized population'. Journal of Nervous and Mental Disease. 196 (1): 71–74. doi:10.1097/NMD.0b013e31815fa4c1. PMID18195645.

References[edit]

1. ^'Judith Herman'. harvard.edu. 16 March 2012. Retrieved 19 April 2018.
2. ^John Marzillier, To Hell and Back (2012) p 302
3. ^John Marzillier, To Hell and Back (2012) p 12 and p 02
4. ^Whealin,Ph.D., Julia M.; Slone,Ph.D., Laurie (22 May 2007). 'National Center for PTSD Fact Sheet: Complex PTSD'. National Center for PTSD, United States Department of Veterans Affairs. Archived from the original on 16 February 2008. Retrieved 15 March 2008.
5. ^Herman, Judith Lewis (1997) [1992], 'A new diagnosis', in Herman, Judith Lewis (ed.), Trauma and recovery: the aftermath of violence - from domestic abuse to political terror, New York: BasicBooks, p. 119, ISBN9780465087303.
6. ^John Marzillier, To Hell and Back (2012) p. 304
7. ^D. Goleman, Emotional Intelligence (1996) p. 210-11
8. ^John Marzillier, To Hell and Back (2012) p. 182
9. ^D. Goleman, Emotional Intelligence (1996) p. 213
10. ^John Marzillier, To Hell and Back (2012) p. 256
11. ^'Conversation with History; Dr. Judith Lewis Herman'. Conversations with History: Institute of International Studies. UC Berkeley. Retrieved December 22, 2007.
12. ^'Center for the Humanities-War: 2009/2010'. deimos3.apple.com.

External links[edit]

J Herman Dmg And Associates

• 'Justice from the Victim's Perspective' - Lecture given at Wesleyen University, 10 May 2010
• 'Conversations with History: The Case of Trauma and Recovery Psychological Insight and Political Understanding with Judith Herman' - Interview with Harry Kreisler from the University of Berkeley, 30 October 2010

J Herman Dmg File